Importance: 
 
The chapter "Acids, bases and salts" carries significant weightage around \(6\) marks, highlighting its significance in the overall curriculum. A clear understanding of this chapter will enhance how acids, bases, and salts interact with each other and their impact on various natural and industrial processes.
 
Question distribution: 
  •  \(1\) marks - One question
  • \(2\) marks - One question
  • \(3\) marks - One question
(Note: The exact mark distribution may vary slightly across examinations)
 
Learning objectives:
  • Understand the pH scale and identify whether substances are acidic, basic, or neutral, with examples from daily life like soil and water quality.
  • Explain neutralisation reactions and relate them to real-world uses such as antacids and soil treatment.
  • Describe how salts are prepared through reactions like neutralisation and identify different types of salts and their applications.
  • Recognise practical uses of acids, bases, and salts in cleaning, digestion, food preservation, and various industries.
 
Neutralisation reaction:
 
\(Acid\ + Base\ → Salt\ + Water\)
 
pH scale:
 
phw923.jpg
pH scale
  • pH - potenz (potential) of hydrogen
  • \(0\) to \(7\) - Acid
  • \(7\) - Neutral
  • \(7\) to \(14\) - Base
 
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Variation of pH
 
 
Importance of pH in everday life:
 
Situation Cause Effect Neutralisation
Insect/Bee sting Formic acid Pain & burning Base (Baking soda/lime paste)
Wasp sting Alkaline Pain & burning Acid (Vinegar)
Nettle sting Methanoic acid Burning pain Base (Rub dock leaf)
Tooth decay Mouth acids Cavity formation Basic toothpaste
Acidity Excess HCl Heartburn/ulcer Antacids (\(Mg(OH)_2\)
Acidic soil Fertilisers Poor plant growth Lime (\(CaO\) or \(Ca(OH)_2\))
Alkaline soil Excess base Poor nutrient availability Acid (Compost)
Industrial waste Acidic effluents Environmental damage Lime or limestone
 
 
Salts:
  • Strong acid + Strong base → Neutral Salt + Water
  • Weak acid + Weak base → Neutral Salt + Water
  • Strong acid + Weak base → Acidic Salt + Water
  • Weak acid + Strong base → Basic Salt + Water
Chemicals from common salt:
 
Common name Chemical name Formula Uses Method of preparation
Common salt Sodium chloride
\(NaCl\)
Raw material for NaOH, baking soda, washing soda; used as food preservative Obtained from sea water & mining of rock salt
Caustic soda Sodium hydroxide
\(NaOH\)
Soaps, detergents, paper Chlor-alkali process: Electrolysis of brine
Bleaching Powder Calcium oxychloride or Calcium hypochlorite
\(CaOCl_2\)
Bleaching agent, disinfectant, water treatment Passing chlorine gas over slaked lime
Baking Soda Sodium hydrogen carbonate or sodium bicarbonate
\(NaHCO_3\)
Baking (release of \(CO_2\)), antacid, fire extinguishers, cleaning Solvay process
Washing Soda Sodium carbonate decahydrate
\(Na_2CO_3.10H_2O\)
Glass, soap, paper industry, water softening Recrystallisation of sodium carbonate/Solvay process
Plaster of Paris Calcium sulphate hemihydrate
\(CaSO_4.1/2H_2O\)
Making casts, statues, chalks, surgical bandages, wall designs Heating gypsum at 373 K
Gypsum Calcium sulphate dihydrate
\(CaSO_4.2H_2O\)
Making POP, cement, agriculture, plastering Naturally occurring mineral or addition of water to POP
 
Water of crystallisation:
The number of water molecules found in the crystalline substance is called water of crystallisation. These salts are known as hydrated salts.
Copper sulphate pentahydrate (Blue vitriol):
 
Blue vitriol contains a total of five water molecules. As a result, its water of crystallisation is \(5\). When blue copper sulphate crystals are gently heated, they lose their five water molecules and transform into colourless anhydrous copper sulphate.
 
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(a) Crystalline hydrated salt   (b) Amorphous anhydrous salt
 
Similarly, ferrous sulphate heptahydrate \(FeSO_4.7H_2O\) from pale green on heating loses the water of crystallisation and changes to white anhydrous salt.
 
Plaster of Paris:
The calcium sulphate hemihydrate is commonly known as plaster of Paris. The name is derived from the place of its origin Montmartre in the Paris district. The chemical formula is .
Preparation of plaster of Paris:
  
When gypsum  is heated in a rotating kiln at \(373 K\), it loses all its water molecule and forms calcium sulphate hemihydrate \(CaSO_4.1/2H_2O\).
 
\(2CaSO_4.2H_2O \xrightarrow {373K}CaSO_4​.1/2​H_2​O + 1.5H_2O\)
 
Properties of plaster of Paris:
  • It is a white colour powder.
  • It acts as an oxidizing agent under extreme conditions.
  • It produces gypsum when mixed with water.
\(CaSO_4.\frac{1}{2}H_{2}O + 1\frac{1}{2}.H_{2}O\rightarrow CaSO_4.2H_2O\)